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Title: Thermodynamic properties of (a propyl ester + an n-alkane) at 298.15 K II. {xC3H7CO2C3H7 + (1 − x)n-CmH2m + 2}, (m = 6 to 10)
Authors: Lorenzana, M. T.
Legido, J. L.
Jiménez, E.
Fernández, J.
Pías, L.
Ortega, J. 
Paz Andrade, M. I.
Issue Date: 1990
Publisher: 0021-9614
Journal: Journal of Chemical Thermodynamics 
Abstract: Excess molar enthalpies HmE and excess molar volumes VmE of (propyl butanoate + an n-alkane) at 298.15 K and atmospheric pressure are presented for the n-alkanes C6 to C10 over the whole mole-fraction range. Values of HmE were determined using a Calvet microcalorimeter, and of VmE from densities measured with a vibrating-tube densimeter. The HmE and VmE values are all positive, increasing with the length of the n-alkane chain. The experimental results are compared with the predictions of several group-contribution models.
ISSN: 0021-9614
DOI: 10.1016/0021-9614(90)90197-X
Source: The Journal of Chemical Thermodynamics[ISSN 0021-9614],v. 22(3), p. 263-268
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