Identificador persistente para citar o vincular este elemento:
http://hdl.handle.net/10553/121188
Campo DC | Valor | idioma |
---|---|---|
dc.contributor.author | Tsunashima, Ryo | en_US |
dc.contributor.author | Long, De-Liang | en_US |
dc.contributor.author | Endo, Toru | en_US |
dc.contributor.author | Noro, Shin-ichiro | en_US |
dc.contributor.author | Akutagawa, Tomoyuki | en_US |
dc.contributor.author | Nakamura, Takayoshi | en_US |
dc.contributor.author | Quesada Cabrera, Raúl | en_US |
dc.contributor.author | McMillan, Paul F. | en_US |
dc.contributor.author | Kogerler, Paul | en_US |
dc.contributor.author | Cronin, Leroy | en_US |
dc.date.accessioned | 2023-03-15T11:45:19Z | - |
dc.date.available | 2023-03-15T11:45:19Z | - |
dc.date.issued | 2011 | en_US |
dc.identifier.issn | 1463-9076 | en_US |
dc.identifier.uri | http://hdl.handle.net/10553/121188 | - |
dc.description.abstract | The Dawson-type polyanion [α-Mo18O54(SO 3)2]4-, with two SO32- templates embedded inside a polyoxomolybdate(vi) cage, exhibits thermochromism over an exceptionally wide temperature range (∼500 K). The temperature dependence of the cluster structure, established from X-ray crystallography, IR and Raman spectroscopy and DFT calculations, is related to a decreasing HOMO-LUMO gap in the near UV with increasing temperature. We postulate this is due to geometrical changes that affect both the occupied and unoccupied frontier molecular orbitals of this cluster anion. | en_US |
dc.language | eng | en_US |
dc.relation.ispartof | Physical Chemistry Chemical Physics | en_US |
dc.source | Physical Chemistry Chemical Physics [ISSN 1463-9076], v. 13(16), p. 7295-7297 | en_US |
dc.subject | 230321 Compuestos organometálicos | en_US |
dc.subject | 221031 Termoquímica | en_US |
dc.subject | 221304 Altas temperaturas | en_US |
dc.title | Exploring the thermochromism of sulfite-embedded polyoxometalate capsules | en_US |
dc.type | info:eu-repo/semantics/Article | en_US |
dc.identifier.doi | 10.1039/c1cp20074g | en_US |
dc.identifier.scopus | 2-s2.0-79953861178 | - |
dc.identifier.isi | WOS:000289203800005 | - |
dc.contributor.orcid | #NODATA# | - |
dc.contributor.orcid | #NODATA# | - |
dc.contributor.orcid | #NODATA# | - |
dc.contributor.orcid | #NODATA# | - |
dc.contributor.orcid | #NODATA# | - |
dc.contributor.orcid | #NODATA# | - |
dc.contributor.orcid | #NODATA# | - |
dc.contributor.orcid | #NODATA# | - |
dc.contributor.orcid | #NODATA# | - |
dc.contributor.orcid | #NODATA# | - |
dc.identifier.issue | 16 | - |
dc.relation.volume | 13 | en_US |
dc.investigacion | Ciencias | en_US |
dc.type2 | Artículo | en_US |
dc.identifier.external | 20436844 | - |
dc.utils.revision | Sí | en_US |
dc.identifier.ulpgc | No | en_US |
dc.contributor.buulpgc | BU-BAS | en_US |
dc.description.sjr | 1,697 | |
dc.description.jcr | 3,573 | |
dc.description.sjrq | Q1 | |
dc.description.jcrq | Q1 | |
dc.description.scie | SCIE | |
item.grantfulltext | none | - |
item.fulltext | Sin texto completo | - |
crisitem.author.dept | GIR IUNAT: Fotocatálisis y espectroscopía para aplicaciones medioambientales. | - |
crisitem.author.dept | IU de Estudios Ambientales y Recursos Naturales | - |
crisitem.author.orcid | 0000-0002-6288-9250 | - |
crisitem.author.parentorg | IU de Estudios Ambientales y Recursos Naturales | - |
crisitem.author.fullName | Quesada Cabrera, Raúl | - |
Colección: | Artículos |
Citas SCOPUSTM
19
actualizado el 24-nov-2024
Citas de WEB OF SCIENCETM
Citations
18
actualizado el 24-nov-2024
Visitas
23
actualizado el 30-mar-2024
Google ScholarTM
Verifica
Altmetric
Comparte
Exporta metadatos
Los elementos en ULPGC accedaCRIS están protegidos por derechos de autor con todos los derechos reservados, a menos que se indique lo contrario.