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Please use this identifier to cite or link to this item: http://hdl.handle.net/10553/121188
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dc.contributor.authorTsunashima, Ryoen_US
dc.contributor.authorLong, De-Liangen_US
dc.contributor.authorEndo, Toruen_US
dc.contributor.authorNoro, Shin-ichiroen_US
dc.contributor.authorAkutagawa, Tomoyukien_US
dc.contributor.authorNakamura, Takayoshien_US
dc.contributor.authorQuesada Cabrera, Raúlen_US
dc.contributor.authorMcMillan, Paul F.en_US
dc.contributor.authorKogerler, Paulen_US
dc.contributor.authorCronin, Leroyen_US
dc.date.accessioned2023-03-15T11:45:19Z-
dc.date.available2023-03-15T11:45:19Z-
dc.date.issued2011en_US
dc.identifier.issn1463-9076en_US
dc.identifier.urihttp://hdl.handle.net/10553/121188-
dc.description.abstractThe Dawson-type polyanion [α-Mo18O54(SO 3)2]4-, with two SO32- templates embedded inside a polyoxomolybdate(vi) cage, exhibits thermochromism over an exceptionally wide temperature range (∼500 K). The temperature dependence of the cluster structure, established from X-ray crystallography, IR and Raman spectroscopy and DFT calculations, is related to a decreasing HOMO-LUMO gap in the near UV with increasing temperature. We postulate this is due to geometrical changes that affect both the occupied and unoccupied frontier molecular orbitals of this cluster anion.en_US
dc.languageengen_US
dc.relation.ispartofPhysical Chemistry Chemical Physicsen_US
dc.sourcePhysical Chemistry Chemical Physics [ISSN 1463-9076], v. 13(16), p. 7295-7297en_US
dc.subject230321 Compuestos organometálicosen_US
dc.subject221031 Termoquímicaen_US
dc.subject221304 Altas temperaturasen_US
dc.titleExploring the thermochromism of sulfite-embedded polyoxometalate capsulesen_US
dc.typeinfo:eu-repo/semantics/Articleen_US
dc.identifier.doi10.1039/c1cp20074gen_US
dc.identifier.scopus2-s2.0-79953861178-
dc.identifier.isiWOS:000289203800005-
dc.contributor.orcid#NODATA#-
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dc.identifier.issue16-
dc.relation.volume13en_US
dc.investigacionCienciasen_US
dc.type2Artículoen_US
dc.identifier.external20436844-
dc.utils.revisionSíen_US
dc.identifier.ulpgcNoen_US
dc.contributor.buulpgcBU-BASen_US
dc.description.sjr1,697
dc.description.jcr3,573
dc.description.sjrqQ1
dc.description.jcrqQ1
dc.description.scieSCIE
item.grantfulltextnone-
item.fulltextSin texto completo-
crisitem.author.deptGIR IUNAT: Fotocatálisis y espectroscopía para aplicaciones medioambientales.-
crisitem.author.deptIU de Estudios Ambientales y Recursos Naturales-
crisitem.author.orcid0000-0002-6288-9250-
crisitem.author.parentorgIU de Estudios Ambientales y Recursos Naturales-
crisitem.author.fullNameQuesada Cabrera, Raúl-
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