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Please use this identifier to cite or link to this item: http://hdl.handle.net/10553/74930
DC FieldValueLanguage
dc.contributor.authorEl-Sepelgy, Osamaen_US
dc.contributor.authorBrzozowska, Aleksandraen_US
dc.contributor.authorAzofra Mesa, Luis Miguelen_US
dc.contributor.authorJang, Yoon Kyungen_US
dc.contributor.authorCavallo, Luigien_US
dc.contributor.authorRueping, Magnusen_US
dc.date.accessioned2020-10-21T12:29:33Z-
dc.date.available2020-10-21T12:29:33Z-
dc.date.issued2017en_US
dc.identifier.issn1433-7851en_US
dc.identifier.urihttp://hdl.handle.net/10553/74930-
dc.description.abstractAn iron-catalyzed cycloisomerization of allenols todeoxygenated pyranose glycals has been developed. Combinedexperimental and computational studies showthat the ironcomplex exhibits adual catalytic role in that the non-innocentcyclopentadienone ligand acts as proton shuttle by initialhydrogen abstraction from the alcohol and by facilitatingprotonation and deprotonation events in the isomerization anddemetalation steps.Molecular orbital analysis provides insightinto the unexpected and selective formation of the 3,4-dihydro-2H-pyran.en_US
dc.languageengen_US
dc.relation.ispartofAngewandte Chemie - International Editionen_US
dc.sourceAngewandte Chemie - International Edition [ISSN 1433-7851], v. 56, p.14863 –14867en_US
dc.subject221001 Catálisisen_US
dc.titleExperimental and Computational Study of an Unexpected Iron-Catalyzed Carboetherification by Cooperative Metal and Ligand Substrate Interaction and Proton Shuttlingen_US
dc.typeinfo:eu-repo/semantics/articleen_US
dc.typeArticleen_US
dc.identifier.doi10.1002/anie.201708240en_US
dc.description.lastpage14867en_US
dc.identifier.issue47-
dc.description.firstpage14863en_US
dc.relation.volume56en_US
dc.investigacionCienciasen_US
dc.type2Artículoen_US
dc.description.numberofpages5en_US
dc.utils.revisionSíen_US
dc.identifier.ulpgcNoen_US
dc.description.sjr6,155
dc.description.jcr12,102
dc.description.sjrqQ1
dc.description.jcrqQ1
dc.description.scieSCIE
item.grantfulltextopen-
item.fulltextCon texto completo-
crisitem.author.deptGIR IUNAT: Fotocatálisis y espectroscopía para aplicaciones medioambientales.-
crisitem.author.deptIU de Estudios Ambientales y Recursos Naturales-
crisitem.author.orcid0000-0003-4974-1670-
crisitem.author.parentorgIU de Estudios Ambientales y Recursos Naturales-
crisitem.author.fullNameAzofra Mesa, Luis Miguel-
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