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http://hdl.handle.net/10553/74777
| Title: | Hydrogenation of CO2-Derived Carbonates and Polycarbonates to Methanol and Diols by Metal-Ligand Cooperative Manganese Catalysis | Authors: | Zubar, Viktoriia Lebedev, Yury Azofra Mesa, Luis Miguel Cavallo, Luigi El-Sepelgy, Osama Rueping, Magnus |
UNESCO Clasification: | 221001 Catálisis | Issue Date: | 2018 | Journal: | Angewandte Chemie - International Edition | Abstract: | The first base-metal-catalysed hydrogenation ofCO2-derived carbonates to alcohols is presented. The reactionproceedsundermildconditionsinthepresenceofawell-defined manganese complex with aloading as lowas0.25 mol%. The non-precious-metal homogenous catalyticsystem provides an indirect route for the conversion of CO2into methanol with the co-production of value-added (vicinal)diols in yields of up to 99%. Experimental and computationalstudies indicate ametal–ligand cooperative catalysis mechanism. | URI: | http://hdl.handle.net/10553/74777 | ISSN: | 1433-7851 | DOI: | 10.1002/anie.201805630 | Source: | Angewandte Chemie - International Edition [ISSN 1433-7851], v. 57, p. 13439 –13443 |
| Appears in Collections: | Artículos |
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