Identificador persistente para citar o vincular este elemento:
http://hdl.handle.net/10553/74777
| Título: | Hydrogenation of CO2-Derived Carbonates and Polycarbonates to Methanol and Diols by Metal-Ligand Cooperative Manganese Catalysis | Autores/as: | Zubar, Viktoriia Lebedev, Yury Azofra Mesa, Luis Miguel Cavallo, Luigi El-Sepelgy, Osama Rueping, Magnus |
Clasificación UNESCO: | 221001 Catálisis | Fecha de publicación: | 2018 | Publicación seriada: | Angewandte Chemie - International Edition | Resumen: | The first base-metal-catalysed hydrogenation ofCO2-derived carbonates to alcohols is presented. The reactionproceedsundermildconditionsinthepresenceofawell-defined manganese complex with aloading as lowas0.25 mol%. The non-precious-metal homogenous catalyticsystem provides an indirect route for the conversion of CO2into methanol with the co-production of value-added (vicinal)diols in yields of up to 99%. Experimental and computationalstudies indicate ametal–ligand cooperative catalysis mechanism. | URI: | http://hdl.handle.net/10553/74777 | ISSN: | 1433-7851 | DOI: | 10.1002/anie.201805630 | Fuente: | Angewandte Chemie - International Edition [ISSN 1433-7851], v. 57, p. 13439 –13443 |
| Colección: | Artículos |
Adobe PDF (1,2 MB)
Los elementos en ULPGC accedaCRIS están protegidos por derechos de autor con todos los derechos reservados, a menos que se indique lo contrario.