Hydrogenation of CO2-Derived Carbonates and Polycarbonates to Methanol and Diols by Metal-Ligand Cooperative Manganese Catalysis

Título:	Hydrogenation of CO2-Derived Carbonates and Polycarbonates to Methanol and Diols by Metal-Ligand Cooperative Manganese Catalysis
Autores/as:	Zubar, Viktoriia Lebedev, Yury Azofra Mesa, Luis Miguel Cavallo, Luigi El-Sepelgy, Osama Rueping, Magnus
Clasificación UNESCO:	221001 Catálisis
Fecha de publicación:	2018
Publicación seriada:	Angewandte Chemie - International Edition
Resumen:	The first base-metal-catalysed hydrogenation ofCO2-derived carbonates to alcohols is presented. The reactionproceedsundermildconditionsinthepresenceofawell-defined manganese complex with aloading as lowas0.25 mol%. The non-precious-metal homogenous catalyticsystem provides an indirect route for the conversion of CO2into methanol with the co-production of value-added (vicinal)diols in yields of up to 99%. Experimental and computationalstudies indicate ametal–ligand cooperative catalysis mechanism.
URI:	http://hdl.handle.net/10553/74777
ISSN:	1433-7851
DOI:	10.1002/anie.201805630
Fuente:	Angewandte Chemie - International Edition [ISSN 1433-7851], v. 57, p. 13439 –13443
Colección:	Artículos

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