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Please use this identifier to cite or link to this item: http://hdl.handle.net/10553/74192
DC FieldValueLanguage
dc.contributor.authorAzofra Mesa, Luis Miguelen_US
dc.contributor.authorTran, Mai Anhen_US
dc.contributor.authorZubar, Viktoriiaen_US
dc.contributor.authorCavallo, Luigien_US
dc.contributor.authorRueping, Magnusen_US
dc.contributor.authorEl-Sepelgy, Osamaen_US
dc.date.accessioned2020-08-31T10:14:49Z-
dc.date.available2020-08-31T10:14:49Z-
dc.date.issued2020en_US
dc.identifier.issn1364-548Xen_US
dc.identifier.otherScopus-
dc.identifier.urihttp://hdl.handle.net/10553/74192-
dc.description.abstractAn unprecedented base metal catalysed asymmetric synthesis of α-chiral amine precursors from racemic alcohols is reported. This redox-neutral reaction utilises a bench-stable manganese complex and Ellman's sulfinamide as a versatile ammonia surrogate. DFT calculations explain the unusual finding of the highly stereoselective transformation enabled by a catalyst that undergoes an unusual dynamic kinetic resolution.en_US
dc.languageengen_US
dc.relation.ispartofChemical Communicationsen_US
dc.sourceChemical communications [EISSN 1364-548X],v. 56 (64), p. 9094-9097, (Agosto 2020)en_US
dc.subject2301 química analíticaen_US
dc.titleConversion of racemic alcohols to optically pure amine precursors enabled by catalyst dynamic kinetic resolution: experiment and computationen_US
dc.typeinfo:eu-repo/semantics/Articleen_US
dc.typeArticleen_US
dc.identifier.doi10.1039/d0cc02881aen_US
dc.identifier.scopus85089358987-
dc.contributor.authorscopusid55142490200-
dc.contributor.authorscopusid57205148829-
dc.contributor.authorscopusid57200544491-
dc.contributor.authorscopusid56465514800-
dc.contributor.authorscopusid8973437600-
dc.contributor.authorscopusid35421840800-
dc.identifier.eissn1364-548X-
dc.description.lastpage9097en_US
dc.identifier.issue64-
dc.description.firstpage9094en_US
dc.relation.volume56en_US
dc.investigacionCienciasen_US
dc.type2Artículoen_US
dc.description.numberofpages4en_US
dc.utils.revisionSíen_US
dc.date.coverdateAgosto 2020en_US
dc.identifier.ulpgcSíen_US
dc.description.sjr1,837
dc.description.jcr6,222
dc.description.sjrqQ1
dc.description.jcrqQ1
dc.description.scieSCIE
item.grantfulltextopen-
item.fulltextCon texto completo-
crisitem.author.deptGIR IUNAT: Fotocatálisis y espectroscopía para aplicaciones medioambientales.-
crisitem.author.deptIU de Estudios Ambientales y Recursos Naturales-
crisitem.author.orcid0000-0003-4974-1670-
crisitem.author.parentorgIU de Estudios Ambientales y Recursos Naturales-
crisitem.author.fullNameAzofra Mesa, Luis Miguel-
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