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Please use this identifier to cite or link to this item: http://hdl.handle.net/10553/69311
DC FieldValueLanguage
dc.contributor.authorVeenboer, Richard M. P.en_US
dc.contributor.authorAzofra Mesa, Luis Miguelen_US
dc.contributor.authorGasperini, Danilaen_US
dc.contributor.authorCollado, Albaen_US
dc.contributor.authorCordes, David B.en_US
dc.contributor.authorSlawin, Alexandra M. Z.en_US
dc.contributor.authorCavallo, Luigien_US
dc.contributor.authorNolan, Steven P.en_US
dc.date.accessioned2020-01-24T09:27:51Z-
dc.date.available2020-01-24T09:27:51Z-
dc.date.issued2019en_US
dc.identifier.issn1477-9226en_US
dc.identifier.otherWoS-
dc.identifier.urihttp://hdl.handle.net/10553/69311-
dc.description.abstractNew [Au(IPr)(CHR2)] complexes have been synthesised through protonolysis reactions of [Au(IPr)(OH)] with moderately acidic substrates, CH2R2. An array of spectroscopic (IR and NMR), structural (X-ray), electronic (DFT) and experimental (reactivity) parameters was collected to quantify the variation in stereoelectronic properties of these new and previously reported [Au(IPr)(CHR2)] complexes. Variation of the R substituents on the carbanion ligands (CHR2-) was found to have a crucial impact on parameters characterising the resulting gold complexes. A regression analysis of both experimental and modelled parameters, guided by network analysis techniques, produced linear models that supported trends within the [Au(IPr)(CHR2)] complexes.en_US
dc.languageengen_US
dc.relation.ispartofDalton Transactionsen_US
dc.sourceDalton Transactions[ISSN 1477-9226],v. 48 (22), p. 7693-7703en_US
dc.subject3303 ingeniería y tecnología químicasen_US
dc.subject.otherN-Heterocyclic Carbeneen_US
dc.subject.otherEquilibrium Aciditiesen_US
dc.subject.otherGold Catalystsen_US
dc.subject.otherCarbon Acidsen_US
dc.subject.otherSubstituenten_US
dc.subject.otherLigandsen_US
dc.subject.otherMetalen_US
dc.subject.otherAuen_US
dc.subject.otherReactivityen_US
dc.subject.otherMechanismen_US
dc.titleRegression analysis of properties of [Au(IPr)(CHR2)] complexesen_US
dc.typeinfo:eu-repo/semantics/Articleen_US
dc.typeArticleen_US
dc.identifier.doi10.1039/c9dt00841aen_US
dc.identifier.scopus85066850530-
dc.identifier.isi000470709700023-
dc.contributor.authorscopusid56515319000-
dc.contributor.authorscopusid55142490200-
dc.contributor.authorscopusid55773018500-
dc.contributor.authorscopusid55761921200-
dc.contributor.authorscopusid8066427800-
dc.contributor.authorscopusid35602399300-
dc.contributor.authorscopusid57204926818-
dc.contributor.authorscopusid7102048183-
dc.identifier.eissn1477-9234-
dc.description.lastpage7703en_US
dc.identifier.issue22-
dc.description.firstpage7693en_US
dc.relation.volume48en_US
dc.investigacionIngeniería y Arquitecturaen_US
dc.type2Artículoen_US
dc.contributor.daisngid5785127-
dc.contributor.daisngid1089199-
dc.contributor.daisngid28176021-
dc.contributor.daisngid1498959-
dc.contributor.daisngid30326073-
dc.contributor.daisngid1572-
dc.contributor.daisngid24922-
dc.contributor.daisngid8491-
dc.utils.revisionSíen_US
dc.contributor.wosstandardWOS:Veenboer, RMP-
dc.contributor.wosstandardWOS:Azofra, LM-
dc.contributor.wosstandardWOS:Gasperini, D-
dc.contributor.wosstandardWOS:Collado, A-
dc.contributor.wosstandardWOS:Cordes, DB-
dc.contributor.wosstandardWOS:Slawin, AMZ-
dc.contributor.wosstandardWOS:Cavallo, L-
dc.contributor.wosstandardWOS:Nolan, SP-
dc.date.coverdateJunio 2019en_US
dc.identifier.ulpgcSíen_US
dc.description.sjr1,048
dc.description.jcr4,174
dc.description.sjrqQ1
dc.description.jcrqQ1
dc.description.scieSCIE
item.grantfulltextopen-
item.fulltextCon texto completo-
crisitem.author.deptGIR IUNAT: Fotocatálisis y espectroscopía para aplicaciones medioambientales.-
crisitem.author.deptIU de Estudios Ambientales y Recursos Naturales-
crisitem.author.orcid0000-0003-4974-1670-
crisitem.author.parentorgIU de Estudios Ambientales y Recursos Naturales-
crisitem.author.fullNameAzofra Mesa, Luis Miguel-
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