|Title:||Enthalpies of mixing at 298.15 K of a methyl alkanoate (from acetate to pentanoate) with n-alkanes (n-tridecane and n-pentadecane)||Authors:||Ortega, J.
Matos, J. S.
Peña, J. A.
|Issue Date:||1990||Publisher:||0040-6031||Journal:||Thermochimica Acta||Abstract:||Excess molar enthalpies hE have been measured for the binary liquid mixtures of four methyl alkanoates (acetate, propanoate, butanoate and pentanoate) with two n-alkanes (n-tridecane and n-pentadecane) at 298.15 K, using an isothermal microcalorimeter. All the mixtures studied were endothermic, the hE values for a given n-alkane decreasing with lengthening of the aliphatic chain of the methyl ester. By contrast, the values of hE increased quasi-regularly as the number of carbon atoms in the n-alkane increased. © 1990.||URI:||http://hdl.handle.net/10553/52147||ISSN:||0040-6031||DOI:||10.1016/0040-6031(90)80631-8||Source:||Thermochimica Acta[ISSN 0040-6031],v. 168, p. 121-126|
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