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Title: Thermodynamic properties of (a methyl ester + an n-alkane). II
Authors: Ortega, J. 
Gonzalez, E.
Matos, J. S.
Legido, J. L.
Issue Date: 1992
Publisher: 0021-9614
Journal: Journal of Chemical Thermodynamics 
Abstract: The present paper reports the excess enthalpies and excess volumes for six examples of {a methyl ester (from ethanoate to n-hexanoate) + n-octane} at the temperature 298.15 K and atmospheric pressure. The excess enthalpies and the excess volumes of all the mixtures were positive over the entire composition range. The magnitudes of both decreased in a quasi-regular manner as the ester chain-length increased. The HEms were analyzed using two versions of the UNIFAC model and the Nitta and Chao model. The overall mean error was 0.13 · HEm. The predicted VEm values obtained using the Nitta and Chao model had a mean error of 0.10 · VEm. © 1992 Academic Press Limited All rights reserved.
ISSN: 0021-9614
DOI: 10.1016/S0021-9614(05)80250-2
Source: The Journal of Chemical Thermodynamics[ISSN 0021-9614],v. 24(1), p. 15-22
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