Please use this identifier to cite or link to this item: http://hdl.handle.net/10553/52099
DC FieldValueLanguage
dc.contributor.authorNavas, Anaen_US
dc.contributor.authorOrtega, Juanen_US
dc.contributor.authorVreekamp, Remkoen_US
dc.contributor.authorMarrero, Elenaen_US
dc.contributor.authorPalomar, Joséen_US
dc.contributor.otherOrtega, Juan-
dc.date.accessioned2018-11-25T17:27:51Z-
dc.date.available2018-11-25T17:27:51Z-
dc.date.issued2009en_US
dc.identifier.issn0888-5885en_US
dc.identifier.urihttp://hdl.handle.net/10553/52099-
dc.description.abstractThis work provides experimental data on liquid-liquid equilibria in the range 288-328 K and data of Hm E and Vm E at temperatures of 298.15 and 318.15 K, for binary mixtures corresponding to 1-butyl-2-methylpyridinium tetrafluoroborate, [b2mpy][BF 4], with alkanols (methanol to pentan-1-ol) and water. The [b2mpy][BF4] is completely miscible in water, and all the mixtures give positive values of Hm E and Vm E, giving increasing values of excess quantities with temperature. For mixtures with alkanols, values of Hm E > 0 are obtained with Vm E < 0 and (dVm E /dT) p > 0. Experimental data are correlated with a suitable equation and are presented together with those obtained in previous works for another two isomers, [b3mpy][BF4] and [b4mpy][BF4], and the properties of all of them are compared and discussed along with their behavior. The quantum-chemical method COSMO-RS is applied for the first time to predict excess properties of these mixtures containing ionic liquids, and the results show a significant contribution of hydrogen bond interactions in the behavior of the mixtures studied here, generically referred to as [bXmpy][BF4] (X ) 2, 3, 4) + H2O or + CvH2v+1(OH) (v = 1-5). © 2009 American Chemical Society.en_US
dc.languageengen_US
dc.publisher0888-5885-
dc.relation.ispartofIndustrial & Engineering Chemistry Researchen_US
dc.sourceIndustrial & Engineering Chemistry Research[ISSN 0888-5885],v. 48 (5), p. 2678-2690en_US
dc.subject.otherDilution Activity-Coefficientsen_US
dc.subject.otherLiquid-Liquid Equilibriaen_US
dc.subject.otherIonic Liquidsen_US
dc.subject.otherInfinite Dilutionen_US
dc.subject.other1-Butyl-3-Methylimidazolium Methylsulfateen_US
dc.subject.otherAlcohols Plusen_US
dc.subject.otherPredictionen_US
dc.subject.otherMixturesen_US
dc.subject.other1,3-Dimethylimidazoliumen_US
dc.subject.otherEnthalpiesen_US
dc.titleExperimental thermodynamic properties of 1-butyl-2-methylpyridinium tetrafluoroborate [b2mpy][BF4] with water and with alkan-1-ol and their interpretation with the COSMO-RS methodologyen_US
dc.typeinfo:eu-repo/semantics/Articleen_US
dc.typeArticleen_US
dc.identifier.doi10.1021/ie8009878en_US
dc.identifier.scopus65349115433-
dc.identifier.isi000263725200045-
dcterms.isPartOfIndustrial & Engineering Chemistry Research-
dcterms.sourceIndustrial & Engineering Chemistry Research[ISSN 0888-5885],v. 48 (5), p. 2678-2690-
dc.contributor.authorscopusid14619607000-
dc.contributor.authorscopusid7402623992-
dc.contributor.authorscopusid36965130200-
dc.contributor.authorscopusid8908650300-
dc.contributor.authorscopusid7003313686-
dc.description.lastpage2690en_US
dc.identifier.issue5-
dc.description.firstpage2678en_US
dc.relation.volume48en_US
dc.type2Artículoen_US
dc.identifier.wosWOS:000263725200045-
dc.contributor.daisngid4942350-
dc.contributor.daisngid170099-
dc.contributor.daisngid4740117-
dc.contributor.daisngid3374374-
dc.contributor.daisngid313977-
dc.identifier.investigatorRIDN-3335-2014-
dc.utils.revisionen_US
dc.contributor.wosstandardWOS:Navas, A-
dc.contributor.wosstandardWOS:Ortega, J-
dc.contributor.wosstandardWOS:Vreekamp, R-
dc.contributor.wosstandardWOS:Marrero, E-
dc.contributor.wosstandardWOS:Palomar, J-
dc.date.coverdateMarzo 2009en_US
dc.identifier.ulpgcen_US
dc.contributor.buulpgcBU-INGen_US
dc.description.jcr1,758
dc.description.jcrqQ2
dc.description.scieSCIE
item.fulltextSin texto completo-
item.grantfulltextnone-
crisitem.author.deptGIR IDeTIC: División de Ingeniería Térmica e Instrumentación-
crisitem.author.deptIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.deptDepartamento de Ingeniería de Procesos-
crisitem.author.orcid0000-0002-8304-2171-
crisitem.author.parentorgIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.fullNameOrtega Saavedra, Juan-
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