Please use this identifier to cite or link to this item: http://hdl.handle.net/10553/48885
Title: Excess molar volumes of (methyl ethanoate + 1-chlorooctane + an n-alkane) ternary mixtures and their constituent binaries at 25°C
Authors: Matos, J. S.
Trenzado, J. L. 
Romano, E. 
Caro, M. N. 
Pérez, M. E.
UNESCO Clasification: 221032 Termodinámica
Keywords: Excess volumes
Binary and ternary mixtures
Methyl ethanoate
n-alkanes
1-chlorooctane, et al
Issue Date: 2001
Publisher: 0095-9782
Journal: Journal of Solution Chemistry 
Abstract: Excess molar volumes, at the temperature 25°C and atmospheric pressure over the whole composition range, are reported for the following binary mixtures: methyl ethanoate + (n-octane, n-decane); methyl ethanoate + 1-chlorooctane; 1-chlorooctane + (n-heptane, n-octane, n-nonane, n-decane); and for the ternary mixtures methyl ethanoate + 1-chlorooctane + (n-heptane, n-octane, n-nonane, n-decane). The values of excess molar volumes were calculated from density and composition results. The excess volumes were utilized to test the multiproperty group-contribution model of Nitta et al. using parameter sets available in the literature. Experimental results from ternary mixtures have also been compared to predictions from several empirical and semiempirical models, which utilize, exclusively, results from binary mixtures.
URI: http://hdl.handle.net/10553/48885
ISSN: 0095-9782
DOI: 10.1023/A:1005279500454
Source: Journal of Solution Chemistry [ISSN 0095-9782], v. 30, p. 263-279
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