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Title: | 1,5-bis-(2,3-dihydroxy-phenylmethylene)-thiocarbohydrazone as reagent for the spectrofluorimetric determination of nanogram amounts of gallium | Authors: | Santana, José J. González-Dávila, Melchor Afonso, Ana M. García-Montelongo, Francisco |
UNESCO Clasification: | 2301 química analítica | Keywords: | Gallium Spectrofluorimetric Bological samples 1,5-bis-(2,3-dihydroxy-phenylmethylene)-thiocarbohydrazone |
Issue Date: | 1990 | Publisher: | 0026-3672 | Journal: | Mikrochimica Acta | Abstract: | A method is developed for the spectrofluorimetric determination of nanogram amounts of gallium using 1,5-bis-(2,3-dihydroxy-phenylmethylene)-thiocarbohydrazone in a 60% (v/v) ethanol-water medium phthalate buffered to pH* 3.5 (λex 400 nm, λem 493 nm, corrected), which allows the determination of 20–100 and 120–600 μg/ml with 1.32 and 0.80 as relative error, respectively, and 5.1 ng·ml−1 as detection limit. Interferences have been evaluated and the method applied to the determination of gallium in samples of bovine liver, heart and kidney. | URI: | http://hdl.handle.net/10553/47194 | ISSN: | 0026-3672 | DOI: | 10.1007/BF01244498 | Source: | Mikrochimica Acta [ISSN 0026-3672], v. 100, p. 55-61 |
Appears in Collections: | Artículos |
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