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Title: | Liquid-liquid equilibria in binary solutions formed by [Pyridinium-Derived][F4B] ionic liquids and alkanols:new experimental data and validation of a multiparametric model for correlating LLE data | Authors: | Espiau, Fernando Ortega, Juan Fernández Suárez, Luis Jesús Wisniak, Jaime |
UNESCO Clasification: | 3303 ingeniería y tecnología químicas 23 Química |
Keywords: | Liquid-liquid equilibrium Ionic Liquids |
Issue Date: | 2011 | Publisher: | 0888-5885 | Journal: | Industrial & Engineering Chemistry Research | Abstract: | Experimental solubility data are presented for a set of binary systems composed of ionic liquids (IL) derived from pyridium, with the tetrafluoroborate anion, and normal alcohols ranging from ethanol to decanol, in the temperature interval of 275 420 K, at atmospheric pressure. For each case, the miscibility curve and the upper critical solubility temperature (UCST) values are presented. The effects of the ILs on the behavior of solutions with alkanols are analyzed, paying special attention to the pyridine derivatives, and considering a series of structural characteristics of the compounds involved. | URI: | http://hdl.handle.net/10553/14593 | ISSN: | 0888-5885 | DOI: | 10.1021/ie201551w | Source: | Industrial & Engineering Chemistry Research[ISSN 0888-5885],v. 50 (21), p. 12259-12270 |
Appears in Collections: | Artículos |
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