Please use this identifier to cite or link to this item: http://hdl.handle.net/10553/134696
Title: Experimental Characterisation and Field Experience of a Reusable, Modified Polyurethane Foam for the Mechanical Clean-Up of Oil Spills on the Sea Surface
Authors: Niehaus, Daniel
Hofmann, Sebastian
Kumar, Srividya Bairamangala
Hoffmann, Marko
Cisneros Aguirre, Jesús 
Schlüter, Michael
UNESCO Clasification: 2510 Oceanografía
330807 Eliminación de residuos
332103 Petróleo crudo
Keywords: Modified polyurethane foam
Oil spill recovery
Oil spill response
Reusable absorbent
Issue Date: 2022
Journal: Journal of Marine Science and Engineering 
Abstract: Oil spills at sea, such as the Deepwater Horizon incident in 2010, are devastating environmental hazards, especially for biodiversity in the maritime ecosystem. In order to help the restoration of coastlines, it is critical to clean the oil up quickly and efficiently with various measures, such as the use of barriers, skimmers, sorbents, dispersing agents, in situ burning, and biological agents. However, most of them still cause high remediation costs; are inefficient, non-reusable, and not environmentally friendly; lack a convenient desorption method; or are simply not yet ready to use in a real-case scenario, where high amounts of hydrocarbons must be removed. Therefore, in this work, a reusable modified polyurethane foam for oil absorption on the sea surface is presented and characterised. Due to a chemical formulation with a special co-polymer, its oleophilic properties are strongly enhanced. Laboratory soaking tests with different oils and a mixture of Louisiana sweet crude oil with artificial sea water (ASW) are conducted. To do so, a pneumatic press with adjustable pressures was used to characterise the foam’s capability to recover oil between 10 and 18 times its own weight for a period of up to 50 consecutive repetitions with a maximum saturation in less than one minute. Sequential trials with different oil mass fractions in ASW determined a decreasing content of recovered ASW with increasing amounts of crude oil, while, in all cases, the total oil recovery rate proved to be more than 90% within one’s standard deviation. Finally, practical applications of sorption methods are presented to give an idea of difficulties encountered in real remediation scenarios.
URI: http://hdl.handle.net/10553/134696
ISSN: 2077-1312
DOI: 10.3390/jmse10101369
Source: Journal of Marine Science and Engineering [ISSN 2077-1312], v. 10, 1369, (Septiembre 2022)
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