Please use this identifier to cite or link to this item: http://hdl.handle.net/10553/130654
Title: Biomimetic photoexcited cobaloxime catalysis in organic synthesis
Authors: Dam, Phong
Zuo, Kaiming
Azofra Mesa, Luis Miguel 
El-Sepelgy, Osama
UNESCO Clasification: 221001 Catálisis
Keywords: Acceptorless dehydrogenation
Electron-Transfer
Alkyl
Dehydrodecarboxylation
Desaturation, et al
Issue Date: 2024
Journal: Angewandte Chemie - International Edition 
Abstract: Drawing inspiration from nature has long been a cornerstone of chemical innovation, with natural systems offering a wealth of untapped potential for discovery. In this minireview, we delve into the burgeoning field of cobaloxime catalysis in organic synthesis, which mimic the catalytic activity of the natural organometallic alkylcobalamine enzymes. Our focus lies on elucidating the latest advancements in this area, as well as delineating the primary mechanistic pathways at play. By describing, and comparing these mechanisms, we provide a comprehensive overview of the current state-of-the-art, while also shedding light on the key unresolved challenges that await further exploration.
URI: http://hdl.handle.net/10553/130654
ISSN: 1433-7851
DOI: 10.1002/anie.202405775
Source: Angewandte Chemie-International Edition [ISSN 1433-7851], (2024)
Appears in Collections:Artículos
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