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http://hdl.handle.net/10553/130654
Title: | Biomimetic photoexcited cobaloxime catalysis in organic synthesis | Authors: | Dam, Phong Zuo, Kaiming Azofra Mesa, Luis Miguel El-Sepelgy, Osama |
UNESCO Clasification: | 221001 Catálisis | Keywords: | Acceptorless dehydrogenation Electron-Transfer Alkyl Dehydrodecarboxylation Desaturation, et al |
Issue Date: | 2024 | Journal: | Angewandte Chemie - International Edition | Abstract: | Drawing inspiration from nature has long been a cornerstone of chemical innovation, with natural systems offering a wealth of untapped potential for discovery. In this minireview, we delve into the burgeoning field of cobaloxime catalysis in organic synthesis, which mimic the catalytic activity of the natural organometallic alkylcobalamine enzymes. Our focus lies on elucidating the latest advancements in this area, as well as delineating the primary mechanistic pathways at play. By describing, and comparing these mechanisms, we provide a comprehensive overview of the current state-of-the-art, while also shedding light on the key unresolved challenges that await further exploration. | URI: | http://hdl.handle.net/10553/130654 | ISSN: | 1433-7851 | DOI: | 10.1002/anie.202405775 | Source: | Angewandte Chemie-International Edition [ISSN 1433-7851], (2024) |
Appears in Collections: | Artículos |
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