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Please use this identifier to cite or link to this item: http://hdl.handle.net/10553/121274
DC FieldValueLanguage
dc.contributor.authorQuesada Cabrera, Raúl-
dc.contributor.authorFirth, Steven-
dc.contributor.authorBlackman, Christopher S.-
dc.contributor.authorLong, De-Liang-
dc.contributor.authorCronin, Leroy-
dc.contributor.authorMcMillan, Paul F.-
dc.date.accessioned2023-03-16T12:30:23Z-
dc.date.available2023-03-16T12:30:23Z-
dc.date.issued2012-
dc.identifier.isbn00224596 1095726X-
dc.identifier.issn0022-4596-
dc.identifier.urihttp://hdl.handle.net/10553/121274-
dc.description.abstractStructural changes occurring within non-conventional Dawson-type [α/β-Mo 18O 54(SO 3) 2] 4- polyanions in the form of tetrapentylammonium salts were studied by a combination of IR, Raman and visible spectroscopy at high temperature and high pressure. Evidence of the formation of bronze-type materials above 400 K and also upon pressurization to 8 GPa is presented. This conclusion is suggested to be a general result for polyoxometalate compounds subjected to extreme conditions and it opens opportunities for the design of new materials with interesting optical and electronic properties.-
dc.languageeng-
dc.relation.ispartofJournal of Solid State Chemistry-
dc.sourceJournal of Solid State Chemistry [ISSN 0022-4596], v. 186, p. 171-176-
dc.subject230321 Compuestos organometálicos-
dc.subject230117 Espectroscopia Ramn-
dc.subject221303 Altas presiones-
dc.subject221304 Altas temperaturas-
dc.subject.otherPolyoxometalates-
dc.subject.otherSpectroscopy-
dc.subject.otherBronze-like species-
dc.subject.otherHigh temperature-
dc.subject.otherHigh pressure-
dc.subject.otherThermochromic properties-
dc.titleSpectroscopic studies of sulfite-based polyoxometalates at high temperature and high pressure-
dc.typeinfo:eu-repo/semantics/Article-
dc.typeArticle-
dc.identifier.doi10.1016/j.jssc.2011.12.005-
dc.identifier.scopus2-s2.0-84856081152-
dc.identifier.isiWOS:000299801400026-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.identifier.issue0-
dc.relation.volume186-
dc.investigacionCiencias-
dc.type2Artículo-
dc.identifier.external20436843-
dc.utils.revisionSí-
dc.identifier.ulpgcNo-
dc.contributor.buulpgcBU-BAS-
dc.description.sjr0,927
dc.description.jcr2,04
dc.description.sjrqQ1
dc.description.jcrqQ2
dc.description.scieSCIE
item.grantfulltextopen-
item.fulltextCon texto completo-
crisitem.author.deptGIR IUNAT: Fotocatálisis y espectroscopía para aplicaciones medioambientales.-
crisitem.author.deptIU de Estudios Ambientales y Recursos Naturales-
crisitem.author.orcid0000-0002-6288-9250-
crisitem.author.parentorgIU de Estudios Ambientales y Recursos Naturales-
crisitem.author.fullNameQuesada Cabrera, Raúl-
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