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Please use this identifier to cite or link to this item: http://hdl.handle.net/10553/121181
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dc.contributor.authorSalamat, Ashkanen_US
dc.contributor.authorHyett, Geoffreyen_US
dc.contributor.authorQuesada Cabrera, Raúlen_US
dc.contributor.authorMcMillan, Paul F.en_US
dc.contributor.authorParkin, Ivan P.en_US
dc.date.accessioned2023-03-15T10:32:19Z-
dc.date.available2023-03-15T10:32:19Z-
dc.date.issued2010en_US
dc.identifier.issn1932-7447en_US
dc.identifier.urihttp://hdl.handle.net/10553/121181-
dc.description.abstractWe report a crystallographic study of Ti2.85O4N, a new titanium oxynitride phase discovered using chemical vapor deposition and combinatorial chemistry techniques, under high-pressure conditions. Synchrotron X-ray diffraction was used to monitor structural changes in the material during compression up to 68 GPa. The data indicate that the orthorhombic (Cmcm) ambient-pressure phase (K0 = 154 ± 22 GPa with K0' = 5.2 ± 0.5) undergoes a first-order transition at 18 GPa to a new orthorhombic (Pmc21) structure. This new high-pressure polymorph remains stable up to 42 GPa, after which the emergence of a second high-pressure monoclinic (P21/c) phase is observed.en_US
dc.languageengen_US
dc.relation.ispartofJournal of Physical Chemistry Cen_US
dc.sourceJournal of Physical Chemistry C [ISSN 1932-7447], v. 114(18), p. 8546-8551en_US
dc.subject220406 Fenómenos de alta presiónen_US
dc.subject221104 Cristalografíaen_US
dc.subject2303 Química inorgánicaen_US
dc.subject.otherChemical structureen_US
dc.subject.otherCompressionen_US
dc.subject.otherMaterialsen_US
dc.subject.otherPhase transitionsen_US
dc.subject.otherPhysical and chemical processesen_US
dc.titleHigh-Pressure Behavior and Polymorphism of Titanium Oxynitride Phase Ti2.85O4Nen_US
dc.typeinfo:eu-repo/semantics/Articleen_US
dc.identifier.doi10.1021/jp100769ren_US
dc.identifier.scopus2-s2.0-77952080970-
dc.identifier.isiWOS:000277280800058-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.identifier.issue18-
dc.relation.volume114en_US
dc.investigacionCienciasen_US
dc.type2Artículoen_US
dc.identifier.external20436850-
dc.utils.revisionSíen_US
dc.identifier.ulpgcNoen_US
dc.contributor.buulpgcBU-BASen_US
dc.description.jcr4,524
dc.description.jcrqQ1
dc.description.scieSCIE
item.grantfulltextopen-
item.fulltextCon texto completo-
crisitem.author.deptGIR IUNAT: Fotocatálisis y espectroscopía para aplicaciones medioambientales.-
crisitem.author.deptIU de Estudios Ambientales y Recursos Naturales-
crisitem.author.orcid0000-0002-6288-9250-
crisitem.author.parentorgIU de Estudios Ambientales y Recursos Naturales-
crisitem.author.fullNameQuesada Cabrera, Raúl-
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