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http://hdl.handle.net/10553/107169
Título: | An Easy Procedure to Quantify Anticoagulant Rodenticides and Pharmaceutical Active Compounds in Soils | Autores/as: | Acosta Dacal, Andrea Carolina Rial Berriel, Cristian Javier Díaz-Díaz, Ricardo Bernal-Suárez, María del Mar Zumbado Peña, Manuel Luis Henríquez Hernández, Luis Alberto Pérez Luzardo, Octavio Luis |
Clasificación UNESCO: | 32 Ciencias médicas 3214 Toxicología |
Palabras clave: | Brodifacoum Flocoumafen Veterinary drugs QuEChERS LC-MS/MS, et al. |
Fecha de publicación: | 2021 | Publicación seriada: | Toxics | Resumen: | A modified QuEChERS (quick, easy, cheap, effective, rugged, and safe) extraction was validated for the extraction of seven coumarin anticoagulant rodenticides (ARs) and 36 pharmaceutical active compounds (PhACs) residues in soil samples using liquid chromatography tandem mass spectrometry (LC-MS/MS). The aim of this work was to develop a method for the monitoring of these compounds in agricultural lands as well as in forensic applications for the determination of ARs poisoning. As far as is known, this is the first time that a QuEChERS-based method is used for the extraction of ARs in soil, as well as on such a quantity of PhACs. A matrix effect study was carried out on samples of soil devoted to agriculture in the midland area of the Canary Islands (clay loam type). It was in house validated (accuracy, precision, and linearity) at seven spiked levels between 0.5 and 50 ng g1. The limits of quantification (LOQ) ranged between 0.5 and 50.0 ng g1 and the limits of detection (LOD) ranged from 0.024 to 6.25 ng g1. The method was then successfully used for both the determination of the target analytes in the soils from the agricultural plots that had been irrigated with regenerated water, and in the soil collected from underneath wild bird carcasses (which had been the subject of forensic investigation). | URI: | http://hdl.handle.net/10553/107169 | ISSN: | 2305-6304 | DOI: | 10.3390/toxics9040083 | Fuente: | Toxics [ISSN 2305-6304], v.9 (4), 83, (Abril 2021) |
Colección: | Artículos |
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