Please use this identifier to cite or link to this item:
http://hdl.handle.net/10553/106993
Title: | A combined experimental and theoretical study on diglyme + 1-alkanol liquid mixtures | Authors: | Trenzado, J. L. Rozas, S. Caro, M. N. Atilhan, M. Aparicio, S. |
UNESCO Clasification: | 220408 Líquidos | Keywords: | Alcohols Glymes Hydrogen Bonding Liquid Mixtures Molecular Simulation, et al |
Issue Date: | 2021 | Project: | RTI2018-101987-B-I00 (Ministerio de Ciencia, Innovación y Universidades ) | Journal: | Journal of Molecular Liquids | Abstract: | The properties, structuring and intermolecular forces of diglyme + alkanol mixtures are studied using a combined experimental and theoretical approach. The thermophysical properties as well as the molecular simulation results provide detailed characterization of the mixtures in terms of composition, type of 1-alkanol and temperature. The possibility of development of heteroassociations by glyme - alkanol hydrogen bonding as well as their effect on the weakening and breaking on alkanols self-association show a pivotal role on the mixtures structure as well as the glyme self-association. The reported mixtures show complex structural effects varying with mixtures composition which may be considered as model of ether – hydroxyl interaction and their effects on the mixture's properties and nature. | URI: | http://hdl.handle.net/10553/106993 | ISSN: | 0167-7322 | DOI: | 10.1016/j.molliq.2021.116048 | Source: | Journal of Molecular Liquids [ISSN 0167-7322], v. 334, 116048, (Julio 2021) |
Appears in Collections: | Artículos |
Items in accedaCRIS are protected by copyright, with all rights reserved, unless otherwise indicated.