Please use this identifier to cite or link to this item:
http://hdl.handle.net/10553/74701
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Azofra Mesa, Luis Miguel | en_US |
| dc.contributor.author | Elguero, José | en_US |
| dc.contributor.author | Alkorta, Ibon | en_US |
| dc.date.accessioned | 2020-10-13T12:46:10Z | - |
| dc.date.available | 2020-10-13T12:46:10Z | - |
| dc.date.issued | 2020 | en_US |
| dc.identifier.issn | 1463-9076 | en_US |
| dc.identifier.other | Scopus | - |
| dc.identifier.uri | http://hdl.handle.net/10553/74701 | - |
| dc.description.abstract | Interanionic H-bonds (IAHBs) are unfavourable interactions in the gas phase becoming favoured when anions are in solution. Dianion dimers are also susceptible to being trapped inside the cavities of cyanostar (CS) macrocycles, and thus, the formation of 2 : 2 anion : cyanostar aggregates is mainly supported by three kinds of interactions: IAHBs between the dianions, π-π stacking between the confronted cyanostars, and the presence of an intricate network of multiple C(sp2)HO H-bonds between cyanostar ligands and the anionic moieties. An analysis of the interaction energies supported by NBO reveals a slight cooperative effect of the CSs on the IAHB stabilisation. | en_US |
| dc.language | eng | en_US |
| dc.relation.ispartof | Physical Chemistry Chemical Physics | en_US |
| dc.source | Physical Chemistry Chemical Physics [EISSN 1463-9084], v. 22 (20), p. 11348-11353, (Mayo 2020) | en_US |
| dc.subject | 2307 Química física | en_US |
| dc.title | Stabilisation of dianion dimers trapped inside cyanostar macrocycles | en_US |
| dc.type | info:eu-repo/semantics/Article | en_US |
| dc.type | Article | en_US |
| dc.identifier.doi | 10.1039/D0CP01321H | en_US |
| dc.identifier.scopus | 85085536137 | - |
| dc.contributor.authorscopusid | 55142490200 | - |
| dc.contributor.authorscopusid | 35474081900 | - |
| dc.contributor.authorscopusid | 7005819296 | - |
| dc.identifier.eissn | 1463-9084 | - |
| dc.description.lastpage | 11353 | en_US |
| dc.identifier.issue | 20 | - |
| dc.description.firstpage | 11348 | en_US |
| dc.relation.volume | 22 | en_US |
| dc.investigacion | Ciencias | - |
| dc.type2 | Artículo | en_US |
| dc.description.numberofpages | 6 | en_US |
| dc.utils.revision | Sí | - |
| dc.date.coverdate | Mayo 2020 | en_US |
| dc.identifier.ulpgc | Sí | - |
| dc.contributor.buulpgc | BU-BAS | en_US |
| dc.description.sjr | 1,053 | |
| dc.description.jcr | 3,676 | |
| dc.description.sjrq | Q1 | |
| dc.description.jcrq | Q1 | |
| dc.description.scie | SCIE | |
| item.grantfulltext | open | - |
| item.fulltext | Con texto completo | - |
| crisitem.author.dept | GIR Fotocatálisis y espectroscopía para aplicaciones medioambientales. Unidad asociada al CSIC a través del Instituto de Ciencias de Materiales de Sevilla | - |
| crisitem.author.dept | IU de Estudios Ambientales y Recursos Naturales | - |
| crisitem.author.orcid | 0000-0003-4974-1670 | - |
| crisitem.author.parentorg | IU de Estudios Ambientales y Recursos Naturales | - |
| crisitem.author.fullName | Azofra Mesa, Luis Miguel | - |
| Appears in Collections: | Artículos | |
Adobe PDF (3,92 MB)
SCOPUSTM
Citations
11
checked on Jun 19, 2022
Page view(s)
58
checked on May 21, 2022
Download(s)
81
checked on May 21, 2022
Google ScholarTM
Check
Altmetric
Share
Export metadata
Items in accedaCRIS are protected by copyright, with all rights reserved, unless otherwise indicated.