Identificador persistente para citar o vincular este elemento: http://hdl.handle.net/10553/63414
Campo DC Valoridioma
dc.contributor.authorFernández Suárez, Luis Jesúsen_US
dc.contributor.authorOrtega Saavedra, Juanen_US
dc.contributor.authorWisniak, Jaimeen_US
dc.date.accessioned2020-01-22T09:52:02Z-
dc.date.available2020-01-22T09:52:02Z-
dc.date.issued2019en_US
dc.identifier.issn0001-1541en_US
dc.identifier.otherScopus-
dc.identifier.otherWoS-
dc.identifier.urihttp://hdl.handle.net/10553/63414-
dc.description.abstractIn this work, a method is proposed to validate the experimental data of solutions of n‐components in vapor–liquid equilibria (VLE) with some nonvolatile component (nv‐VLE). The methodology is based on the resolution of the differential Gibbs–Duhem equation using two forms (differential and integral) described in a previous work. The combination of both forms evaluates as many relationships between the variables that define each data series in equilibrium (p, T, x1, … , n‐1, y1, … , n‐1) as degrees of freedom the problem has, although in this work it is only necessary to use the integral form. The proposed method is applied to 70 experimental data series published in the literature, considering the numerical limits previously assigned to parameters established for the integral‐form, according to the following. (a) A parameter ψ is identified as p or T according to if the data are iso‐T or iso‐p; (b) verification of the data is assessed by the difference urn:x-wiley:00011541:media:aic16628:aic16628-math-0005, with urn:x-wiley:00011541:media:aic16628:aic16628-math-0006 > 0, and urn:x-wiley:00011541:media:aic16628:aic16628-math-0007 is determined by an uncertainty procedure of the inconsistency function urn:x-wiley:00011541:media:aic16628:aic16628-math-0008, being urn:x-wiley:00011541:media:aic16628:aic16628-math-0009; and (c) The parameter κψ depends on the type of equilibrium. With κψ = 5, the rejection ratio of the total analyzed is 12%, this percentage increases as the level of quality required increases above 31% for κψ = 3. The calculations require a precise representation of the binomial {data+model}, which produces excellent results for the treatment of nv‐VLE and the properties of solutions, whose parametrization is achieved by an advanced procedure of combined optimization.en_US
dc.languageengen_US
dc.relation.ispartofAIChE journalen_US
dc.sourceAiche Journal[ISSN 0001-1541],v. 65 (8)en_US
dc.subject3303 ingeniería y tecnología químicasen_US
dc.subject.otherModelingen_US
dc.subject.otherConsistency‐testen_US
dc.subject.otherNonvolatile compoundsen_US
dc.subject.otherVLEen_US
dc.subject.otherThermodinamic propertiesen_US
dc.titleExtension of the validation method for vapor–liquid equilibrium data to systems with nonvolatile componentsen_US
dc.typeinfo:eu-repo/semantics/articleen_US
dc.typeArticleen_US
dc.identifier.doi10.1002/aic.16628en_US
dc.identifier.scopus85065989935-
dc.identifier.isi000477082000001-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.contributor.authorscopusid35112937200-
dc.contributor.authorscopusid7402623992-
dc.contributor.authorscopusid7102458505-
dc.identifier.eissn1547-5905-
dc.identifier.issue8-
dc.relation.volume65en_US
dc.investigacionIngeniería y Arquitecturaen_US
dc.type2Artículoen_US
dc.contributor.daisngid2736231-
dc.contributor.daisngid170099-
dc.contributor.daisngid55744-
dc.utils.revisionen_US
dc.contributor.wosstandardWOS:Fernandez, L-
dc.contributor.wosstandardWOS:Ortega, J-
dc.contributor.wosstandardWOS:Wisniak, J-
dc.date.coverdateAgosto 2019en_US
dc.identifier.ulpgces
dc.description.sjr0,947
dc.description.jcr3,519
dc.description.sjrqQ1
dc.description.jcrqQ2
dc.description.scieSCIE
item.fulltextSin texto completo-
item.grantfulltextnone-
crisitem.author.deptGIR IDeTIC: División de Ingeniería Térmica e Instrumentación-
crisitem.author.deptIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.deptDepartamento de Ingeniería de Procesos-
crisitem.author.deptGIR IDeTIC: División de Ingeniería Térmica e Instrumentación-
crisitem.author.deptIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.deptDepartamento de Ingeniería de Procesos-
crisitem.author.orcid0000-0002-6924-3444-
crisitem.author.orcid0000-0002-8304-2171-
crisitem.author.parentorgIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.parentorgIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.fullNameFernández Suárez, Luis Jesús-
crisitem.author.fullNameOrtega Saavedra, Juan-
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