Identificador persistente para citar o vincular este elemento: http://hdl.handle.net/10553/55058
Campo DC Valoridioma
dc.contributor.authorHerrera Rodriguez, Carmenen_US
dc.contributor.authorFernández Suárez, Luis Jesúsen_US
dc.contributor.authorOrtega Saavedra, Juanen_US
dc.contributor.authorLópez Tosco, Saraen_US
dc.contributor.authorSosa Marco, Adrielen_US
dc.date.accessioned2019-02-18T16:20:22Z-
dc.date.available2019-02-18T16:20:22Z-
dc.date.issued2019en_US
dc.identifier.issn0888-5885en_US
dc.identifier.otherScopus-
dc.identifier.urihttp://hdl.handle.net/10553/55058-
dc.description.abstractThis work shows a new approach to the parameter-fitting problem useful in the solutions thermodynamic field, providing a more objective framework to obtain better empirical/semiempirical models for chemical engineering applications. A model based on the excess Gibbs energy function gE is used to represent the behavior of real solutions, together with its first derivative hE, using a combined modeling under the paradigm of multiobjective optimization. The problem is formulated as an MINLP methodology to simultaneously consider two aspects: the model complexity and the best parametrization to prevent the overfitting, controlling the trade-off between them by applying the Akaike Information Criterion to gE residuals. Two different solvers, one deterministic (SBB/CONOPT) and another evolutionary (GA), are used, and their ability to solve the problem is analyzed. The designed methodology is applied to three highlighted VLE cases in chemical engineering, and the results obtained show the ability of the method to get the best model in each case. The proposed methodology proved useful for modulating the number of parameters considering the imposed requirements, which decrease as the accuracy requirements for hE are relaxed. The efficient-fronts obtained show a small trade-off region, noting that the proposed framework provides the simplest models with the minimum completeness uncertainty.en_US
dc.languageengen_US
dc.relation.ispartofIndustrial & Engineering Chemistry Researchen_US
dc.sourceIndustrial & Engineering Chemistry Research [ISSN 0888-5885], v. 58 (2), p. 973-983, (Enero 2019)en_US
dc.subject3303 ingeniería y tecnología químicasen_US
dc.subject.otherPlus wateren_US
dc.subject.otherternary-sistemsen_US
dc.subject.otherExcess molar enthalpiesen_US
dc.subject.otherEthil-Acetate-Ethanolen_US
dc.subject.otherBinary-Sistemsen_US
dc.subject.otherPhase-Equilibriaen_US
dc.subject.otherModified Unifac Modelen_US
dc.titleDesign of the Distillation-Extraction Tandem to Separate Ethyl Propanoate from Heptane Solutions Using Pyridinium-Derived Organic Salts as Entrainers. Its Use as a Potential Bioactive Compounden_US
dc.typeinfo:eu-repo/semantics/Articleen_US
dc.typeArticleen_US
dc.identifier.doi10.1021/acs.iecr.8b03986en_US
dc.identifier.scopus85060184096-
dc.identifier.isi000456351200051-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.contributor.authorscopusid57205431952-
dc.contributor.authorscopusid35112937200-
dc.contributor.authorscopusid7402623992-
dc.contributor.authorscopusid16836621400-
dc.contributor.authorscopusid57188754800-
dc.description.lastpage983en_US
dc.identifier.issue2-
dc.description.firstpage973en_US
dc.relation.volume58en_US
dc.investigacionIngeniería y Arquitecturaen_US
dc.type2Artículoen_US
dc.contributor.daisngid4028809-
dc.contributor.daisngid2736231-
dc.contributor.daisngid170099-
dc.contributor.daisngid3564115-
dc.contributor.daisngid27977009-
dc.utils.revisionen_US
dc.contributor.wosstandardWOS:Herrera, C-
dc.contributor.wosstandardWOS:Fernandez, L-
dc.contributor.wosstandardWOS:Ortega, J-
dc.contributor.wosstandardWOS:Lopez-Tosco, S-
dc.contributor.wosstandardWOS:Sosa, A-
dc.date.coverdateEnero 2019en_US
dc.identifier.ulpgces
dc.description.sjr0,899
dc.description.jcr3,573
dc.description.sjrqQ1
dc.description.jcrqQ2
dc.description.scieSCIE
item.fulltextSin texto completo-
item.grantfulltextnone-
crisitem.author.deptGIR IDeTIC: División de Ingeniería Térmica e Instrumentación-
crisitem.author.deptIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.deptDepartamento de Ingeniería de Procesos-
crisitem.author.deptGIR IDeTIC: División de Ingeniería Térmica e Instrumentación-
crisitem.author.deptIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.deptDepartamento de Ingeniería de Procesos-
crisitem.author.deptGIR IDeTIC: División de Ingeniería Térmica e Instrumentación-
crisitem.author.deptIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.orcid0000-0002-6924-3444-
crisitem.author.orcid0000-0002-8304-2171-
crisitem.author.orcid0000-0003-2409-4307-
crisitem.author.orcid0000-0001-5064-0565-
crisitem.author.parentorgIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.parentorgIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.parentorgIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.fullNameHerrera Rodriguez, Carmen-
crisitem.author.fullNameFernández Suárez, Luis Jesús-
crisitem.author.fullNameOrtega Saavedra, Juan-
crisitem.author.fullNameLópez Tosco, Sara-
crisitem.author.fullNameSosa Marco,Adriel-
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