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Title: | Thermodynamic properties of (a methyl ester + an n-alkane). III | Authors: | Ortega, J. Gonzalez, E. |
UNESCO Clasification: | 2213 Termodinámica | Keywords: | Excess-Enthalpies Volumes Prediction Model |
Issue Date: | 1993 | Publisher: | 0021-9614 | Journal: | Journal of Chemical Thermodynamics | Abstract: | The excess molar thermodynamic properties HEm and VEm of {xCH3(CH2)u-1CO2CH3 (u=1 to 6) + (1-x)CH3(CH2)8CH3} have been determined experimentally at the temperature 298.15 K. The general behaviour is similar to that of other (an ester + an alkane) mixtures, the values of HEm and VEm being positive for all these mixtures at all mole fractions. Both decrease quasi-regular as the ester chain-length increases. The results are analysed in terms of several group-contribution theories. © 1993 Academic Press Ltd. | URI: | http://hdl.handle.net/10553/52135 | ISSN: | 0021-9614 | DOI: | 10.1006/jcht.1993.1157 | Source: | The Journal of Chemical Thermodynamics[ISSN 0021-9614],v. 25(4), p. 495-501 |
Appears in Collections: | Artículos |
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