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http://hdl.handle.net/10553/52134
Title: | Thermodynamic properties of (a methyl ester + an n-alkane). V | Authors: | Ortega, J. Gonzalez, E. |
Issue Date: | 1993 | Publisher: | 0021-9614 | Journal: | Journal of Chemical Thermodynamics | Abstract: | Excess molar enthalpies and excess molar volumes for six mixtures: {a methyl ester (from ethanoate to heptanoate) + tetradecane} have been determined at T = 298.15 K as a function of the mole fraction. All the mixtures studied exhibit positive values for both quantities which decrease quasi-exponentially with length of the methyl-ester chain. Several theoretical models were used to obtained the excess quantities, but the Flory and Nitta et al. models predict the excess molar volumes only poorly. © 1993 Academic Press Ltd. | URI: | http://hdl.handle.net/10553/52134 | ISSN: | 0021-9614 | DOI: | 10.1006/jcht.1993.1106 | Source: | The Journal of Chemical Thermodynamics[ISSN 0021-9614],v. 25(9), p. 1083-1088 |
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