Please use this identifier to cite or link to this item: http://hdl.handle.net/10553/52087
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dc.contributor.authorOmar, Salama
dc.contributor.authorLemus, Jesus
dc.contributor.authorRuiz, Elia
dc.contributor.authorFerro, Víctor R.
dc.contributor.authorOrtega, Juan
dc.contributor.authorPalomar, Jose
dc.contributor.otherFerro, Victor
dc.contributor.otherOrtega, Juan
dc.date.accessioned2018-11-25T17:22:02Z-
dc.date.available2018-11-25T17:22:02Z-
dc.date.issued2014
dc.identifier.issn1520-6106
dc.identifier.urihttp://hdl.handle.net/10553/52087-
dc.description.abstractThe use of ionic liquid mixtures (IL-IL mixtures) is being investigated for fine solvent properties tuning of the IL-based systems. The scarce available studies, however, evidence a wide variety of mixing behaviors (from almost ideal to strongly nonideal), depending on both the structure of the IL components and the property considered. In fact, the adequate selection of the cations and anions involved in IL-IL mixtures may ensure the absence or presence of two immiscible liquid phases. In this work, a systematic computational study of the mixing behavior of IL-IL systems is developed by means of COSMO-RS methodology. Liquid-liquid equilibrium (LLE) and excess enthalpy (H-E) data of more than 200 binary IL-IL mixtures (including imidazolium-, pyridinium-, pyrrolidinium-, ammonium-, and phosphonium-based ILs) are calculated at different temperatures, comparing to literature data when available. The role of the interactions between unlike cations and anions on the mutual miscibility/immiscibility of IL-IL mixtures was analyzed. On the basis of proposed guidelines, a new class of immiscible IL-IL mixtures was reported, which only is formed by imidazolium-based compounds.
dc.publisher1520-6106
dc.relation.ispartofJournal of Physical Chemistry B
dc.sourceJournal of Physical Chemistry B[ISSN 1520-6106],v. 118, p. 2442-2450
dc.subject.otherN-Butylpyridinium Tetrafluoroborate
dc.subject.otherBinary-Mixtures
dc.subject.otherCosmo-Rs
dc.subject.otherThermodynamic Properties
dc.subject.otherAliphatic-Hydrocarbons
dc.subject.otherPhysical-Properties
dc.subject.otherCarbon-Dioxide
dc.subject.otherEquilibria
dc.subject.otherExtraction
dc.subject.otherPrediction
dc.titleIonic liquid mixtures - An analysis of their mutual miscibility
dc.typeinfo:eu-repo/semantics/Articlees
dc.typeArticlees
dc.identifier.doi10.1021/jp411527b
dc.identifier.scopus84897678356
dc.identifier.isi000332756200016
dcterms.isPartOfJournal Of Physical Chemistry B
dcterms.sourceJournal Of Physical Chemistry B[ISSN 1520-6106],v. 118 (9), p. 2442-2450
dc.contributor.authorscopusid7101977684
dc.contributor.authorscopusid35559127900
dc.contributor.authorscopusid36742174100
dc.contributor.authorscopusid7005269426
dc.contributor.authorscopusid7402623992
dc.contributor.authorscopusid7003313686
dc.description.lastpage2450
dc.description.firstpage2442
dc.relation.volume118
dc.type2Artículoes
dc.identifier.wosWOS:000332756200016
dc.contributor.daisngid2176031
dc.contributor.daisngid563768
dc.contributor.daisngid31445972
dc.contributor.daisngid1991724
dc.contributor.daisngid1216094
dc.contributor.daisngid170099
dc.contributor.daisngid313977
dc.identifier.investigatorRIDI-2462-2015
dc.identifier.investigatorRIDN-3335-2014
dc.contributor.wosstandardWOS:Omar, S
dc.contributor.wosstandardWOS:Lemus, J
dc.contributor.wosstandardWOS:Ruiz, E
dc.contributor.wosstandardWOS:Ferro, VR
dc.contributor.wosstandardWOS:Ortega, J
dc.contributor.wosstandardWOS:Palomar, J
dc.date.coverdateMarzo 2014
dc.identifier.ulpgces
dc.description.sjr1,44
dc.description.jcr3,302
dc.description.sjrqQ1
dc.description.jcrqQ2
item.grantfulltextnone-
item.fulltextSin texto completo-
crisitem.author.deptIDeTIC: División de Ingeniería Térmica e Instrumentación-
crisitem.author.deptIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.deptIngeniería de Procesos-
crisitem.author.orcid0000-0002-8304-2171-
crisitem.author.parentorgIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.fullNameOrtega Saavedra, Juan-
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