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http://hdl.handle.net/10553/48880
Title: | Thermophysical behavior and temperature effect on the N-methylpyrrolidone + (C1-C10) alkan-1-ols mixed solvents | Authors: | García, Begoña Alcalde, Rafael Aparicio, Santiago Leal, José M. Trenzado, José L. |
UNESCO Clasification: | 2204 Física de fluidos | Keywords: | Eras Model-Calculations Binary-Liquid Mixtures Excess Molar Volumes 298.15 K Cyclohexane Plus, et al |
Issue Date: | 2003 | Publisher: | 0888-5885 | Journal: | Industrial & Engineering Chemistry Research | Abstract: | Densities and dynamic viscosities of the N-methylpyrrolidone/(C1−C10) alkan-1-ols mixed solvents were measured at atmospheric pressure and 293.15, 303.15, 313.15, and 323.15 K over the whole composition range. The excess and mixing properties deduced from these data were interpreted in terms of intermolecular interactions and structural effects. The Soave−Redlich−Kwong and Peng−Robinson cubic equations of state and the modified extended real associated solution (ERAS) and the Prigogine−Flory−Patterson (PFP) models were used to correlate the excess molar volumes. Several correlation viscosity models were also used in data reduction. | URI: | http://hdl.handle.net/10553/48880 | ISSN: | 0888-5885 | DOI: | 10.1021/ie0205602 | Source: | Industrial and Engineering Chemistry Research [ISSN 0888-5885], v. 42, p. 920-928 |
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