Please use this identifier to cite or link to this item: http://hdl.handle.net/10553/48577
DC FieldValueLanguage
dc.contributor.authorOrtega, J.en_US
dc.contributor.authorToledo-Marante, F. J.en_US
dc.contributor.otherOrtega, Juan-
dc.date.accessioned2018-11-23T23:02:55Z-
dc.date.available2018-11-23T23:02:55Z-
dc.date.issued2002en_US
dc.identifier.issn0021-9614en_US
dc.identifier.urihttp://hdl.handle.net/10553/48577-
dc.description.abstractThis paper presents H-m(E) and V-m(E) measurements taken at T = 298.15 K and at the atmospheric pressure of 100.65 kPa for 22 binary mixtures composed of one of four ethyl esters (methanoate, ethanoate, propanoate, and pentanoate) and one of seven alkane isomers, C-6 to C-8. The H-m(E) of four binary mixtures of ethyl propanoate and pentanoate with n-C-6 and n-C-8, measured at the conditions mentioned above are also presented. The results indicate that the mixing process is endothermic for all the mixtures, with H-m(E) varying regularly with the components chain length, increasing with alkane chain length and decreasing with the acid chain length in the ester. The V-m(E) values vary also regularly in a manner similar to that of the H-m(E.) slight contractions are observed for (ethyl pentanoate + 2-methylpentane). A new form of a polynomial equation used previously was employed to correlate the experimental values of the excess quantities and yielded good results in all cases. In addition, the behaviour of these mixtures is explained in terms of an interaction model proposed in previous work. (C) 2002 Elsevier Science Ltd. All rights reserved.en_US
dc.languageengen_US
dc.publisher0021-9614-
dc.relation.ispartofJournal of Chemical Thermodynamicsen_US
dc.sourceJournal Of Chemical Thermodynamics[ISSN 0021-9614],v. 34 (9), p. 1439-1459en_US
dc.subject3303 ingeniería y tecnología químicasen_US
dc.subject.otherExcess Molar Volumesen_US
dc.subject.otherMethyl N-Alkanoatesen_US
dc.subject.otherBinary-Mixturesen_US
dc.subject.other298.15-Ken_US
dc.subject.otherEnthalpiesen_US
dc.subject.otherV=1en_US
dc.titleThermodynamic properties of (an ethyl ester plus a branched alkane). XV. H-m(E) and V-m(E) values for (an ester plus an alkane)en_US
dc.typeinfo:eu-repo/semantics/Articleen_US
dc.typeArticleen_US
dc.identifier.doi10.1016/S0021-9614(02)00199-4en_US
dc.identifier.scopus0035981629-
dc.identifier.isi000179070800009-
dcterms.isPartOfJournal Of Chemical Thermodynamics-
dcterms.sourceJournal Of Chemical Thermodynamics[ISSN 0021-9614],v. 34 (9), p. 1439-1459-
dc.contributor.authorscopusid7402623992-
dc.contributor.authorscopusid6508338024-
dc.description.lastpage1459en_US
dc.identifier.issue9-
dc.description.firstpage1439en_US
dc.relation.volume34en_US
dc.investigacionIngeniería y Arquitecturaen_US
dc.type2Artículoen_US
dc.identifier.wosWOS:000179070800009-
dc.contributor.daisngid170099-
dc.contributor.daisngid7665963-
dc.identifier.investigatorRIDN-3335-2014-
dc.utils.revisionen_US
dc.contributor.wosstandardWOS:Ortega, J-
dc.contributor.wosstandardWOS:Toledo-Marante, FJ-
dc.date.coverdateSeptiembre 2002en_US
dc.identifier.ulpgcen_US
dc.contributor.buulpgcBU-INGen_US
dc.description.jcr1,0
dc.description.jcrqQ1
dc.description.scieSCIE
item.fulltextSin texto completo-
item.grantfulltextnone-
crisitem.author.deptGIR IDeTIC: División de Ingeniería Térmica e Instrumentación-
crisitem.author.deptIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.deptDepartamento de Ingeniería de Procesos-
crisitem.author.orcid0000-0002-8304-2171-
crisitem.author.orcid0000-0002-7842-591X-
crisitem.author.parentorgIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.fullNameOrtega Saavedra, Juan-
crisitem.author.fullNameToledo Marante, Francisco Javier-
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