Please use this identifier to cite or link to this item: http://hdl.handle.net/10553/47125
DC FieldValueLanguage
dc.contributor.authorFranco-Barrios, Alejandroen_US
dc.contributor.authorTorres-Padrón, María Estheren_US
dc.contributor.authorSosa-Ferrera, Zoraidaen_US
dc.contributor.authorSantana-Rodríguez, José Juanen_US
dc.contributor.otherTorres-Padron, Maria Esther-
dc.contributor.otherZoraida, Sosa-Ferrera-
dc.date.accessioned2018-11-23T11:02:43Z-
dc.date.available2018-11-23T11:02:43Z-
dc.date.issued2014en_US
dc.identifier.issn1060-3271en_US
dc.identifier.urihttp://hdl.handle.net/10553/47125-
dc.description.abstractA method is presented for the extraction, preconcentration, and determination of two commonly used booster biocides, Irgarol 1051 and diuron, in samples of muscle and liver tissues from Mugil cephalus by microwave-assisted extraction (MAE) followed by SPE for the preconcentration and cleanup step, coupled with LC/MS/MS. The optimum conditions for MAE were established as power 200 W and irradiation time 4 min. Using these conditions, the LOD was 0.13 ng/g for diuron and 0.10 ng/g for Irgarol 1051. The recoveries calculated at three concentration levels (0.5, 5, and 50 ng/g) were greater than 74%. Repeatability was less than 7.5% and reproducibility less than 12.7%. The optimized method was used to monitor these compounds in M. cephalus from different harbors of Gran Canaria Island. The samples were collected bimonthly and processed following the optimized method. High levels of Irgarol 1051 (6.9 ± 1.03 ng/g) were found in the liver, while diuron was undetected. However, diuron was found in the muscle (1.41 ± 0.45 ng/g). The proposed sentinel organism could be used in tropical and subtropical regions to continuously biomonitor for booster biocides over long periods of time. This technique could be a useful tool for improving the management of ocean and coastal waters.en_US
dc.languageengen_US
dc.publisher1060-3271-
dc.relation.ispartofJournal of AOAC Internationalen_US
dc.sourceJournal of AOAC International [ISSN 1060-3271], v. 97, p. 197-204en_US
dc.subject2301 química analíticaen_US
dc.subject.otherLc-Ms/Ms
dc.subject.otherAquatic Organisms
dc.subject.otherPaint Biocides
dc.subject.otherSewage-Sludge
dc.subject.otherHealth-Risk
dc.subject.otherBioaccumulation
dc.subject.otherPollutants
dc.subject.otherIrgarol-1051
dc.subject.otherChemicals
dc.subject.otherBiology
dc.titleDevelopment and application of a microwave-assisted extraction and LC/MS/MS methodology to the determination of antifouling booster biocides in sea mullets (Mugil cephalus) organismsen_US
dc.typeinfo:eu-repo/semantics/Articlees
dc.typeArticlees
dc.identifier.doi10.5740/jaoacint.12-391
dc.identifier.scopus84893649382-
dc.identifier.isi000331496600026-
dcterms.isPartOfJournal Of Aoac International-
dcterms.sourceJournal Of Aoac International[ISSN 1060-3271],v. 97 (1), p. 197-204-
dc.contributor.authorscopusid56029908500-
dc.contributor.authorscopusid8452532700-
dc.contributor.authorscopusid6602897915-
dc.contributor.authorscopusid56248783900-
dc.description.lastpage204-
dc.description.firstpage197-
dc.relation.volume97-
dc.investigacionCienciasen_US
dc.type2Artículoen_US
dc.identifier.wosWOS:000331496600026-
dc.contributor.daisngid20751755-
dc.contributor.daisngid2812385-
dc.contributor.daisngid22437017
dc.contributor.daisngid770178-
dc.contributor.daisngid745012-
dc.contributor.daisngid10914640
dc.identifier.investigatorRIDE-9038-2012-
dc.identifier.investigatorRIDN-1602-2014-
dc.identifier.externalWOS:000331496600026-
dc.contributor.wosstandardWOS:Franco-Barrios, A
dc.contributor.wosstandardWOS:Torres-Padron, ME
dc.contributor.wosstandardWOS:Sosa-Ferrera, Z
dc.contributor.wosstandardWOS:Santana-Rodriguez, JJ
dc.date.coverdateEnero 2014
dc.identifier.ulpgces
dc.description.sjr0,442
dc.description.jcr1,12
dc.description.sjrqQ2
dc.description.jcrqQ3
dc.description.scieSCIE
item.grantfulltextnone-
item.fulltextSin texto completo-
crisitem.author.deptGIR Análisis Químico Medioambiental-
crisitem.author.deptIU de Estudios Ambientales y Recursos Naturales-
crisitem.author.deptDepartamento de Química-
crisitem.author.deptGIR Análisis Químico Medioambiental-
crisitem.author.deptIU de Estudios Ambientales y Recursos Naturales-
crisitem.author.deptDepartamento de Química-
crisitem.author.deptGIR Análisis Químico Medioambiental-
crisitem.author.deptIU de Estudios Ambientales y Recursos Naturales-
crisitem.author.deptDepartamento de Química-
crisitem.author.orcid0000-0001-7000-4419-
crisitem.author.orcid0000-0003-3003-3607-
crisitem.author.orcid0000-0002-5635-7215-
crisitem.author.parentorgIU de Estudios Ambientales y Recursos Naturales-
crisitem.author.parentorgIU de Estudios Ambientales y Recursos Naturales-
crisitem.author.parentorgIU de Estudios Ambientales y Recursos Naturales-
crisitem.author.fullNameTorres Padrón, María Esther-
crisitem.author.fullNameSosa Ferrera, María Zoraida-
crisitem.author.fullNameSantana Rodríguez, José Juan-
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