Please use this identifier to cite or link to this item: http://hdl.handle.net/10553/133216
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dc.contributor.authorPlácido Suarez, Joséen_US
dc.contributor.authorOrtega Saavedra, Juanen_US
dc.contributor.authorKehiaian, Henry V.en_US
dc.date.accessioned2024-09-16T08:22:31Z-
dc.date.available2024-09-16T08:22:31Z-
dc.date.issued1995en_US
dc.identifier.issn1265-1532en_US
dc.identifier.urihttp://hdl.handle.net/10553/133216-
dc.description.abstractEnthalpy-of-mixing, HE, measurements are reported at 298.15 Kfor 1-ch/oroalkanes (1-chlorobutane through 1- chlorononane) + trichloromethane or + 1,1,2,2- tetrachloroethane The mixtures containing 1-chlorobutane are exothermic. HE increases with the chain length of the J-chloroalkane becoming negative/positive or positive for J,1,2,2-tetrachloroethane + 1-chlorooctane or + 1- chlorononane. The experimental HE data are not reproduced by the Modified UNIFAC group contribution method (Dortmund version), using the parameters published in 1993, mainly because of having neglected the group proximity effect. The DISQUAC mode� with dispersive parameters changing regularly with the structure of the molecules, describes fairly well both the magnitude and the shape of the experimental HE curves.en_US
dc.languageengen_US
dc.relation.ispartofELDATA: International Electronic Journal of Physico-Chemistry Dataen_US
dc.sourceELDATA: International Electronic Journal of Physical-Chemistry Data, n. 1, p. 239-248en_US
dc.subject3311 tecnología de la instrumentaciónen_US
dc.subject3328 Procesos tecnológicosen_US
dc.titleExcess enthalpies of 12 binary liquid mixtures of trichloromethane or 1,1,2,2-tetrachloroethane + 1-chloroalkanes (C4 - C9) at 298.15 Ken_US
dc.typeinfo:eu-repo/semantics/articleen_US
dc.typeArticleen_US
dc.investigacionIngeniería y Arquitecturaen_US
dc.type2Artículoen_US
dc.description.numberofpages10en_US
dc.utils.revisionen_US
dc.identifier.ulpgcen_US
dc.contributor.buulpgcBU-INGen_US
item.grantfulltextopen-
item.fulltextCon texto completo-
crisitem.author.deptGIR IDeTIC: División de Ingeniería Térmica e Instrumentación-
crisitem.author.deptIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.deptDepartamento de Ingeniería de Procesos-
crisitem.author.orcid0000-0001-6801-735X-
crisitem.author.orcid0000-0002-8304-2171-
crisitem.author.parentorgIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.fullNamePlácido Suarez, José-
crisitem.author.fullNameOrtega Saavedra, Juan-
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