Please use this identifier to cite or link to this item:
http://hdl.handle.net/10553/133216
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Plácido Suarez, José | en_US |
dc.contributor.author | Ortega Saavedra, Juan | en_US |
dc.contributor.author | Kehiaian, Henry V. | en_US |
dc.date.accessioned | 2024-09-16T08:22:31Z | - |
dc.date.available | 2024-09-16T08:22:31Z | - |
dc.date.issued | 1995 | en_US |
dc.identifier.issn | 1265-1532 | en_US |
dc.identifier.uri | http://hdl.handle.net/10553/133216 | - |
dc.description.abstract | Enthalpy-of-mixing, HE, measurements are reported at 298.15 Kfor 1-ch/oroalkanes (1-chlorobutane through 1- chlorononane) + trichloromethane or + 1,1,2,2- tetrachloroethane The mixtures containing 1-chlorobutane are exothermic. HE increases with the chain length of the J-chloroalkane becoming negative/positive or positive for J,1,2,2-tetrachloroethane + 1-chlorooctane or + 1- chlorononane. The experimental HE data are not reproduced by the Modified UNIFAC group contribution method (Dortmund version), using the parameters published in 1993, mainly because of having neglected the group proximity effect. The DISQUAC mode� with dispersive parameters changing regularly with the structure of the molecules, describes fairly well both the magnitude and the shape of the experimental HE curves. | en_US |
dc.language | eng | en_US |
dc.relation.ispartof | ELDATA: International Electronic Journal of Physico-Chemistry Data | en_US |
dc.source | ELDATA: International Electronic Journal of Physical-Chemistry Data, n. 1, p. 239-248 | en_US |
dc.subject | 3311 tecnología de la instrumentación | en_US |
dc.subject | 3328 Procesos tecnológicos | en_US |
dc.title | Excess enthalpies of 12 binary liquid mixtures of trichloromethane or 1,1,2,2-tetrachloroethane + 1-chloroalkanes (C4 - C9) at 298.15 K | en_US |
dc.type | info:eu-repo/semantics/article | en_US |
dc.type | Article | en_US |
dc.investigacion | Ingeniería y Arquitectura | en_US |
dc.type2 | Artículo | en_US |
dc.description.numberofpages | 10 | en_US |
dc.utils.revision | Sí | en_US |
dc.identifier.ulpgc | Sí | en_US |
dc.contributor.buulpgc | BU-ING | en_US |
item.grantfulltext | open | - |
item.fulltext | Con texto completo | - |
crisitem.author.dept | GIR IDeTIC: División de Ingeniería Térmica e Instrumentación | - |
crisitem.author.dept | IU para el Desarrollo Tecnológico y la Innovación | - |
crisitem.author.dept | Departamento de Ingeniería de Procesos | - |
crisitem.author.orcid | 0000-0001-6801-735X | - |
crisitem.author.orcid | 0000-0002-8304-2171 | - |
crisitem.author.parentorg | IU para el Desarrollo Tecnológico y la Innovación | - |
crisitem.author.fullName | Plácido Suarez, José | - |
crisitem.author.fullName | Ortega Saavedra, Juan | - |
Appears in Collections: | Artículos |
Page view(s)
13
checked on Oct 5, 2024
Download(s)
52
checked on Oct 5, 2024
Google ScholarTM
Check
Share
Export metadata
Items in accedaCRIS are protected by copyright, with all rights reserved, unless otherwise indicated.