Please use this identifier to cite or link to this item: http://hdl.handle.net/10553/57981
DC FieldValueLanguage
dc.contributor.authorAbranches, Dinis O.en_US
dc.contributor.authorSilva, Liliana P.en_US
dc.contributor.authorMartins, Mónia A.R.en_US
dc.contributor.authorFernández Suárez, Luis Jesúsen_US
dc.contributor.authorPinho, Simão P.en_US
dc.contributor.authorCoutinho, João A.P.en_US
dc.date.accessioned2019-11-20T12:27:20Z-
dc.date.available2019-11-20T12:27:20Z-
dc.date.issued2019en_US
dc.identifier.issn0378-3812en_US
dc.identifier.urihttp://hdl.handle.net/10553/57981-
dc.description.abstractThe high melting point of a large number of organic salts with potential ionic liquid-like properties, hinders their applicability as solvents. Considering the success of cholinium chloride on lowering the melting temperature of several substances and its success on forming deep eutectic solvents, this work studies its mixing with organic chlorides to lower their melting points producing eutectic ionic liquids. The solid-liquid phase diagrams for binary mixtures composed of cholinium chloride and ten organic halides were experimentally measured. Surprisingly, cholinium chloride presented, for all these systems, significant positive deviations from ideal liquid behaviour that restricted its ability to lower the melting points of these mixtures. Only for mixtures with ammonium chloride, tetramethylammonium chloride, bis(2-hydroxyethyl)dimethylammonium chloride or cholinium bromide was cholinium chloride able to significantly lower the melting point of the mixture, but without reaching values close to room temperature (298 K). For a better understanding of the results obtained, the solid-liquid phase diagrams of four alkylammonium chloride-based mixtures were experimentally assessed and used to show that these compounds are better than cholinium chloride at inducing negative deviations from ideality, leading to greater melting point depressions.en_US
dc.languageengen_US
dc.relation.ispartofFluid Phase Equilibriaen_US
dc.sourceFluid Phase Equilibria[ISSN 0378-3812],v. 493, p. 120-126, (Agosto 2019)en_US
dc.subject3303 ingeniería y tecnología químicasen_US
dc.subject.otherCholinium chlorideen_US
dc.subject.otherIonic liquiden_US
dc.subject.otherIonic liquid mixturesen_US
dc.subject.otherEutectic solventsen_US
dc.subject.otherSolid-liquid equilibriaen_US
dc.titleCan cholinium chloride form eutectic solvents with organic chloride-based salts?en_US
dc.typeinfo:eu-repo/semantics/Articleen_US
dc.typeArticleen_US
dc.identifier.doi10.1016/j.fluid.2019.04.019en_US
dc.identifier.scopus85067284846-
dc.identifier.isi000470338600012-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.contributor.orcid#NODATA#-
dc.contributor.authorscopusid57209311204-
dc.contributor.authorscopusid57193772351-
dc.contributor.authorscopusid56191802400-
dc.contributor.authorscopusid35112937200-
dc.contributor.authorscopusid7003570175-
dc.contributor.authorscopusid56962705900-
dc.description.lastpage126en_US
dc.description.firstpage120en_US
dc.relation.volume493en_US
dc.investigacionIngeniería y Arquitecturaen_US
dc.type2Artículoen_US
dc.contributor.daisngid30245457-
dc.contributor.daisngid7284401-
dc.contributor.daisngid3115117-
dc.contributor.daisngid2736231-
dc.contributor.daisngid710602-
dc.contributor.daisngid25595360-
dc.utils.revisionen_US
dc.contributor.wosstandardWOS:Abranches, DO-
dc.contributor.wosstandardWOS:Silva, LP-
dc.contributor.wosstandardWOS:Martins, MAR-
dc.contributor.wosstandardWOS:Fernandez, L-
dc.contributor.wosstandardWOS:Pinho, SP-
dc.contributor.wosstandardWOS:Coutinho, JAP-
dc.date.coverdateAgosto 2019en_US
dc.identifier.ulpgces
dc.description.sjr0,762
dc.description.jcr2,838
dc.description.sjrqQ1
dc.description.jcrqQ2
dc.description.scieSCIE
item.grantfulltextnone-
item.fulltextSin texto completo-
crisitem.author.deptGIR IDeTIC: División de Ingeniería Térmica e Instrumentación-
crisitem.author.deptIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.deptDepartamento de Ingeniería de Procesos-
crisitem.author.orcid0000-0002-6924-3444-
crisitem.author.parentorgIU para el Desarrollo Tecnológico y la Innovación-
crisitem.author.fullNameFernández Suárez, Luis Jesús-
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