|Title:||Volumetric behaviour of binary systems of cyclohexane with the hexanol isomers at 298.15 K||Authors:||Ortega, J.
Matos, J. S.
|Issue Date:||1991||Publisher:||0040-6031||Journal:||Thermochimica Acta||Abstract:||Excess molar volumes, vE, based on density measurements taken at 298.15 K, were calculated for ten binary mixtures consisting of cyclohexane and the following isomers of hexanol: 3,3-dimethylbutan-1-ol, 2,2-dimethylbutan-1-ol, 2,3-dimethylbutan-1-ol, 2-ethylbutan-1-ol, 3-methylpentan-1-ol, 4-methylpentan-1-ol, 3,3-dimethylbutan-1-ol, 2-methylpentan-3-ol, hexan-3-ol and 2,3-dimethylbutan-2-ol. The vE values were positive over the entire range of concentration, except in the case of the binary system of x1 cyclohexane + x2 3-methylpentan-1-ol, for which the vE values were negative for x1 < 0.1. A discussion of the behaviour of these mixtures, based on the experimental results, is included. © 1991.||URI:||http://hdl.handle.net/10553/52142||ISSN:||0040-6031||DOI:||10.1016/0040-6031(91)80369-T||Source:||Thermochimica Acta[ISSN 0040-6031],v. 180, p. 1-8|
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