Please use this identifier to cite or link to this item: http://hdl.handle.net/10553/48582
Title: X. Mixing enthalpies of (methyl, or ethyl acrylate + an n-alkane)
Authors: Plácido, J.
Ortega, J. 
Toledo, F. J. 
Keywords: Modified Unifac Model
Excess-Enthalpies
Binary-Mixtures
Methacrylate
Cyclohexane, et al
Issue Date: 1998
Publisher: 0021-9614
Journal: Journal of Chemical Thermodynamics 
Abstract: The excess molar enthalpies HEm have been measured for mixtures containing methyl, or ethyl acrylates with odd n-alkanes (from pentane to heptadecane) at the temperature 298.15 K. The HEm values are positive for all mixtures, increasing regularly with the alkane chain length and decreasing with the ester chain length. The behaviour of these mixtures is justified on the basis of molecular association in acrylates. The theoretical estimation of the excess enthalpies is also carried out using one group contribution model. © 1998 Academic Press.
URI: http://hdl.handle.net/10553/48582
ISSN: 0021-9614
DOI: 10.1006/jcht.1998.0347
Source: Journal Of Chemical Thermodynamics[ISSN 0021-9614],v. 30 (7), p. 805-813
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