Please use this identifier to cite or link to this item: http://hdl.handle.net/10553/47185
Title: Analysis of binary mixtures of 3,3′,4,4′-tetrachlorobiphenyl and 2,3,7,8-tetrachlorodibenzofuran by derivative synchronous fluorescence spectrometry in organized media
Authors: Rodríguez, J. J.Santana 
Ferrera, Z. Sosa 
García, J. Hernández
Martín-Lázaro, A. J.Bermejo
UNESCO Clasification: 2301 química analítica
Keywords: Derivative synchronous fluorescence spectrometry
Polychlorinated biphenyl
Polychlorinated dibenzofurans
3,3’, 4,4’-tetrachlorobiphenyl
2,3,7,8-tetrachlorodibenzo-firan
Micellar media
Sea- water
Issue Date: 1994
Publisher: 0003-2654
Journal: Analyst (London. 1877. Print) 
Abstract: The spectrofluorimetric characteristics of 3,3′,4,4′-tetrachlorobiphenyl (TTCB) and 2,3,7,8-tetrachlorodibenzofuran (TTCDF) were studied in aqueous medium and in the presence of cationic, anionic and non-ionic surfactants. It has been established that the fluorescence of binary mixtures of TTCB and TTCDF is enhanced in polyoxyethylene(10)lauryl ether (POLE) using derivative synchronous fluorescence spectrometry at Δλ= 48 nm. Limits of detection of 5.3 ng ml–1 and 2.7 ng ml–1 are obtained, respectively. Good recoveries are obtained when the method is applied to the analysis of binary mixtures of these compounds added to sea-water.
URI: http://hdl.handle.net/10553/47185
ISSN: 0003-2654
DOI: 10.1039/AN9941902241
Source: The Analyst [ISSN 0003-2654], v. 119, p. 2241-2246
Appears in Collections:Artículos

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