Please use this identifier to cite or link to this item: http://hdl.handle.net/10553/47184
Title: Fluorescence behaviour of polychlorinated dibenzofurans in organized molecular systems. Analytical applications
Authors: Hernández García, Jorge
Sosa Ferrera, Zoraida 
Bermejo Martín-Lázaro, Angel J.
Santana Rodríguez, José J. 
UNESCO Clasification: 2301 química analítica
Keywords: Spectrofluorimetry
2,3,7,8-tetrachlorodibenzofuran
Polyoxyethylene (10) lauryl ether
C12E10
Polychlorinated dibenzofurans
Micellar media
Seawater
Issue Date: 1995
Publisher: 0026-3672
Journal: Mikrochimica Acta 
Abstract: Fluorescence characteristics of several polychlorinated dibenzofurans (PCDFs) of toxicological and environmental interest in the presence of cationic, anionic, neutral surfactants, α-cyclodextrin and β-cyclodextrin were examined. The fluorescence enhancement of 2,3,7,8-tetrachlorodibenzofuran (TTCDF) in the presence of polyoxyethylene(10) lauryl ether (C12E10) medium was utilized to establish a sensitive spectrofluorimetric method for determination of TTCDF. The optimization of variables as the concentration of surfactant, percentage of organic solvent and temperature, and effect of possible interferences from other PCDFs, polychlorinated dibenzo-p-dioxins (PCCDs), polychlorinated biphenyls (PCBs) and Arochlors were investigated. The method, which has a detection limit of 1.30 ng ml−1, has been applied to the determination of TTCDF in sea water with acceptable recoveries.
URI: http://hdl.handle.net/10553/47184
ISSN: 0026-3672
DOI: 10.1007/BF01244358
Source: Mikrochimica Acta [ISSN 0026-3672], v. 118, p. 185-196
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